2-Bromoethyl 2-chloro-6-methylquinoline-3-carboxylate
نویسندگان
چکیده
In the title compound, C(13)H(11)BrClNO(2), the two rings of the quinoline group are fused in an axial fashion at a dihedral angle of 1.28 (9)°. In the crystal, molecules are arranged in zigzag layers along the c axis. The crystal packing is stabilized by weak C-H⋯O hydrogen bonds and inter-molecular inter-actions between Br and O atoms [Br⋯O= 3.076 (2) Å], resulting in the formation of a three-dimensional network.
منابع مشابه
Crystal structure of ethyl 2-chloro-6-methylquinoline-3-carboxylate
In the title compound, C13H12ClNO2, the dihedral angle between the planes of the quinoline ring system (r.m.s. deviation = 0.029 Å) and the ester group is 54.97 (6)°. The C-O-C-Cm (m = meth-yl) torsion angle is -140.62 (16)°. In the crystal, mol-ecules inter-act via aromatic π-π stacking [shortest centroid-centroid separation = 3.6774 (9) Å] generating (010) sheets.
متن کامل2-Chloro-6-methylquinoline-3-carbaldehyde
The quinolinyl fused-ring of the title compound, C(11)H(8)ClNO, is almost planar (r.m.s. deviation = 0.013 Å); the formyl group is slightly bent out of the plane of the fused ring system [C-C-C-O torsion angle = 13.5 (4)°].
متن کامل2-Chloro-7-methylquinoline-3-carbaldehyde
The quinoline fused-ring system of the title compound, C(11)H(8)ClNO, is planar (r.m.s. deviation = 0.007 Å); the formyl group is bent slightly out of the plane [C-C-C-O torsion angles = -9.6 (5) and 170.4 (3)°].
متن کامل4-Azido-2-chloro-6-methylquinoline
In the title compound, C(10)H(7)ClN(4), the quinoline ring system is planar [maximum deviation 0.0035 (10) Å]. The crystal structure is stabilized by van der Waals and π-π stacking inter-actions [centroid-centroid distance 3.6456 (17) Å].
متن کاملEthyl 1-(4-chlorobenzyl)-3-(4-fluorophenyl)-1H-pyrazole-5-carboxylate
In the title compound, C(19)H(16)ClFN(2)O(2), the pyrazole ring makes dihedral angles of 5.15 (6) and 77.72 (6)°, with the fluoro-phenyl and chloro-phenyl rings, respectively.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010